This video capture from Die Hard: With a Vengeance shows Zeus Carver for the first time in the movie. He's running his shop wqhen he sees John McClane (Bruce Willis) outside on the street with a very racial sign around his body.

  Here Samuel L. Jackson is talking to John McClane and warning him about wearing the sign in that neighborhood.

  This one shows you that Bruce Willis is wearing a sign, you just can't read it here.

  These next two movie scene are after they team up to run all over town on a wild goose chase that the bad guys have set up.

  This last scene is when Zeus Carver is captured and held hostage by the bad guys.